Full transcript
Introduction
0:00This is the periodic table of the chemical elements.
0:02Beautiful, isn’t it?
0:04I bet you have already seen it hundred times.
0:07There are 118 chemical elements in this table.
0:11The elements are ordered according to their atomic number, which is the number of protons
0:16in their nucleus.
0:17The lightest elements (hydrogen, helium) are those with lowest atomic number, which means
0:24lowest number of protons; and as we move along the rows and the columns of the table, the
0:29atomic number increases.
0:30But… have you ever asked yourself, what is the origin of all these elements?
0:35How are they produced?
0:36Do they form all in the same way, or through different mechanisms?
0:40Watch this video and you will find out the answer!
0:44Hydrogen, helium, carbon, oxygen… all these names are very familiar to us.
Overview of the Periodic Table
0:57These are some of the most common chemical elements that we can find on Earth, and also
1:02in the Universe.
1:03But have you ever wondered how did they form?
1:06Did they all exist from the Big Bang, or did they form through some specific processes?
1:11Which of them are naturally occurring and which ones are not?
1:15To answer this question, we need to analyse the periodic table starting from the lightest
1:20elements: hydrogen and helium.
Lightest Element
1:23Hydrogen is the lightest element in the Universe: one atom of this element contains only one
1:27proton and one electron.
1:28There are also two slightly different “versions” of this element, known as “isotopes”:
1:33the deuterium, in which the nucleus has one proton and one neutron, and the tritium, where
1:38the nucleus has one proton and two neutrons (all of them have one electron as well).
1:45Helium is the second lightest element: an atom of helium contains two protons and two
1:49electrons (and a few neutrons too, depending on the isotope).
1:53These two are the simplest chemical elements, and also the most abundant ones: in fact,
1:58together they account nearly all ordinary matter in the Universe.
2:02And they are also the oldest!
2:03In fact, the origin of these two elements dates back to the very beginning of the Universe,
2:08about 14 billion years ago: the Big Bang.
2:11Immediately after the Big Bang, the Universe was very hot and dense.
2:15Too much, indeed: in these conditions, chemical elements were not able to form yet, because
2:20protons, neutrons and electrons were moving too fast and they were not able to recombine
2:25together and to form atoms.
2:27As the early Universe kept expanding, it also kept cooling down.
2:31As the temperature decreased, particles started moving slower and slower, and the temperature
2:36became low enough for protons and neutrons to form hydrogen and helium nuclei: this process
2:42is called nucleosynthesis, and it occurred in the first 3 minutes of life of the Universe.
2:47At this point, however, electrons were still moving too fast, and the nuclei were not able
2:53to capture them to form atoms.
2:55For this process to occur, we need to wait approximately 380,000 years after the Big
Big Bang Nucleosynthesis
3:00Bang.
3:01At that time, in fact, the temperature became low enough to allow nuclei to capture electrons
3:06and finally form the very first atoms of hydrogen and helium: this moment is known as “recombination”.
3:13Very tiny amounts of lithium (the third lightest element, having 3 protons and 3 electrons)
3:19were also produced at this time.
3:22So, this is how hydrogen and helium were formed.
3:25The next three elements in the periodic table (lithium, beryllium and boron, having respectively
3:303, 4 and 5 protons in their nuclei), have a totally different origin.
3:34In fact, these three elements are mostly produced in a process known as “cosmic ray spallation”.
3:41What is it?
3:42You may already know that the Earth is constantly bombarded by high-energy particles (mainly,
3:47but not only, protons) coming from space, known as “cosmic rays”.
3:52When these cosmic rays reach our atmosphere, they interact with the atoms and molecules
3:56present there, breaking them apart and leading to the formation of new atoms and particles
4:01through chain reactions.
Formation of Lithium, Beryllium, and Boron
4:03Most of the lithium, beryllium and boron that we find on Earth are produced exactly through
4:07this mechanism.
4:08That’s also why scientists observe a “shortage” of these three elements when they analyse
4:13the composition of the Universe: it’s because they are almost only produced through these
4:18collisions between cosmic rays and other particles, so they are relatively less abundant than
4:24other elements, in the Universe.
4:25Ok, we have seen how the five lightest elements formed.
4:29What about the others?
4:31To understand the origin of the heavier elements, we have to look at what happens inside stars.
4:36A star can be thought as a giant “power plant”, producing enormous quantities of
4:41energy all the time.
4:43The process responsible for the creation of such huge amounts of energy is the nuclear
4:48fusion, which occurs in the core of the star.
4:51In the simplest nuclear fusion reaction, two nuclei of hydrogen (so, two protons) fuse
4:56together into a nucleus of helium.
Role of Cosmic Rays in Element Formation
4:59However, the mass of the final nucleus of helium is smaller than the sum of the initial
5:04masses of the two hydrogen nuclei: this means that part of the mass has been converted into
5:10energy, according to Einstein’s famous equation , where is the mass that has been converted,
5:18is the speed of light and is the energy released.
5:22If you plug in numbers, you will find out that even for a very tiny amount of mass converted,
5:27the amount of energy released is huge!
5:30With this nuclear fusion process, therefore, helium nuclei are produced.
5:34This continues for billion years, until the core of the star runs out of hydrogen.
5:39What next?
5:40Well, the star can then “change” type of fuel… and it starts burning helium instead!
5:45In fact, when the conditions of temperature and pressure become right, helium fusion occurs:
5:51nuclei of helium fuse together forming nuclei of heavier elements, such as carbon (6 protons)
5:57and oxygen (8 protons), and releasing energy again.
6:01So, with this new type of nuclear fusion, the star is able to continue to produce energy
6:06and live for a while.
6:08And what happens when the star runs out of helium as well?
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6:26So, what happens when a star runs out of helium?
Nuclear Fusion in Stars
6:30For low-mass stars, such as our Sun, this means the end of their life: nuclear fusion
6:35stops, and as there is no more “fuel” to be burnt, the star is no longer able to
6:40produce energy.
6:41As a consequence, the outer layers of the star are expelled into space, forming a “planetary
6:47nebula”, while the core remains as a white dwarf.
6:50For high-mass stars, however, something different happens.
6:53In fact, in the collapsing core of these enormous stars, very extreme conditions of temperature
6:58and pressure are reached.
7:00And in these extreme conditions, it becomes possible for nuclei of elements heavier than
7:04helium to undergo nuclear fusion.
7:07So, in a sort of cascade process, the star can burn in sequence carbon, oxygen, nitrogen,
7:13and so on.
7:15As each of these elements undergo nuclear fusion, nuclei of heavier elements are produced.
7:20However, this process does not continue forever.
7:23In fact, the last element that is produced by this mechanism is iron: a nucleus of iron
7:28has 26 protons.
7:31Iron is quite a special element.
7:32In fact, the nuclear fusion of iron is not energetically convenient.
7:37What does it mean?
7:38We say previously that in the fusion of hydrogen into helium, energy is released, because the
7:43mass of the final product is less than the sum of the masses of the initial nuclei.
7:48The same is true for the nuclear fusion of helium, carbon, oxygen, and so on.
7:53However, for iron, this is not true.
7:55In fact, when two nuclei of iron fuse together… they absorb energy, instead of releasing it!
Supernova and Element Creation
8:02This means that when the core is full of iron, the star is no longer able to produce energy…
8:08because the nuclear fusion of iron does not produce energy.
8:11So, this is the beginning of the end, for the star: the core collapses once more, and
8:16it eventually explodes in what is known as “supernova event”.
8:20So, nuclear reactions in the core of stars are able to produce all elements up to iron,
8:26which has an atomic number of 26.
8:28Then, what about all the heavier elements?
8:31How are they produced?
8:33Elements heavier than iron cannot be produced through nuclear fusion, because as we have
8:37seen, this process is not energetically convenient.
8:41In order to be produced, these elements require conditions even more extreme than those found
8:46inside the core of stars.
8:48And these conditions are found when supernova explosions happen.
8:52In a supernova explosion, the material in the outer layers of the star is violently
8:56expelled to the outer space.
8:59During this powerful explosion, the nuclei of the elements previously produced in the
9:04nuclear reactions inside the core continuously collide with different particles, such as
9:09neutrons (also present in the star).
9:12Therefore, thanks to the extreme conditions, the nuclei of these elements are able to “capture”
9:17some of these neutrons.
9:19When this occurs, these nuclei transform into heavier isotopes of the same element (remember:
9:25isotopes are nuclei having same number of protons, but different number of neutrons).
9:31As these nuclei accumulate neutrons, they become more and more unstable, and eventually
9:37decay in a process known as beta-decay, in which neutrons turn into protons.
9:42As a result, some of the nuclei undergoing this process will eventually end up having
9:47more than 26 protons (so, heavier than iron!).
9:50This phenomenon is known as “r-process”, or “rapid neutron-capture process”.
Formation of Elements Heavier than Iron
9:57There is also a variation of this process, known as “s-process”, or “slow neutron-capture
10:02process”, which is essentially the same but occurs much slower, and so the nuclei
10:07decay before being able to capture too many neutrons.
10:11During a supernova explosion, there is one more process that contributes to the production
10:15of elements heavier than iron.
10:17This is known as “p-process”, in which the nuclei expelled during the supernova event
10:23capture protons instead of neutrons, producing therefore nuclei of elements heavier than
10:29iron.
10:30So, summarizing: hydrogen and helium were produced after the Big Bang.
10:34Lithium, beryllium and boron are produced through cosmic ray spallation.
10:39Elements up to iron are produced in the nuclear fusion reactions inside the core of high-mass
10:44stars, while heavier elements are produced during supernova explosions.
10:48So, did we explained the origin of all the elements in the periodic table?
10:53Not yet.
10:54In fact, the heaviest element that can be produced during a supernova explosion is plutonium.
10:59A nucleus of plutonium has 94 protons.
11:02However, if we look again at the periodic table, we see that there are a few elements
Synthetic Elements
11:07heavier than plutonium.
11:08So the question is, how are those elements produced?
11:12The answer is: not naturally…
11:13In fact, they are produced by humans!
11:16Yes, all the elements with more than 94 protons do not exist in nature.
11:20All of them are synthetic, which means that they have been created in laboratory.
11:26Producing atoms of these heavy elements can only be done exploiting difficult and expensive
11:30processes.
11:31For instance, americium (atomic number 95) is produced by bombarding uranium and plutonium
11:37with neutrons in nuclear reactors, while nobelium (atomic number 102) can only be produced in
11:43particle accelerators.
11:45To give you an idea of how precious these elements are, think about this: the price
11:50of one gram of californium (the element having 98 protons in its nucleus) is about 60 million
11:57dollars!
11:58So… we have finally seen how all chemical elements of the periodic table formed.
12:02It’s really amazing to see how different their origin was… and we can say that it’s
12:07because of these differences between them that the Universe look so diverse!
12:12"This video ends here!
12:14Thanks for watching everyone!
12:15Did you find the origin of chemical elements interesting?
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