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【高校化学】酸塩基反応I(理系向け中和反応)【無機化学#4】

受験メモ山本 · 3,686 words · 17 min read

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0:00Hello . Today , we will be discussing the

0:02theory of chemical reactions in the

0:03field of chemical science . As mentioned

0:05in the previous lesson , chemical

0:06reactions in the field of chemical

0:08science can be classified into six main

0:09types . So , from now on , we will learn

0:11the mechanisms of these six types of

0:13reactions in order so that we can

0:15create chemical reaction equations for

0:17each . First , let's look at the first

0:19reaction , the three-postponement

0:21reaction . Furthermore , if we further

0:23divide these three-postponement

0:24reactions into two types ,

0:26neutralization reactions and weakly

0:27advantageous reactions . So , this time ,

0:29we will focus on the first half , which

0:31is to be able to write the reaction

0:32equation for the neutralization

0:34reaction . Now , let's get into the

0:35content . By the way , some of you may

0:38think that we covered neutral reactions

0:40in basic science . That's right , this

0:43time , I think there will be quite a bit

0:45of review . However , there are two main

0:48reasons for this . First , I would like

0:52you to review the basics together . And

0:55the second point , since this is finally

0:57a science class , I'd like to include

0:58some more detailed information . Even if

1:01you've watched the intermediate

1:02reactions in the Basic Science course ,

1:04I'd be happy if you could join me .

1:06Instead , I'll make this a short video ,

1:08so let's do our best together . So , the

1:11main focus will be on how to write

1:13intermediate reactions , but first ,

1:15let's review the 3 - cycle period . Okay ?

1:18First , let's review the definition of

1:20the 3 - cycle period . Yes . 3. Asit , Enki ,

1:23Base . Let's take a look at these . First

1:26, the definition of Alenews . In the

1:28definition of Alenews , 3 is something

1:30that releases H + . And Eki is something

1:32that releases OH - . On the other hand ,

1:35the definition of Brenset , which is a

1:37more recent definition , is something

1:39that gives H + to others , and Eki is

1:41something that receives H + . The reason

1:44for this definition is that , for

1:45example , in the Eki period , there are

1:47things like ammonia . When that reacts

1:51in the machine , we are mainly

1:53considering the aqueous solution , so

1:54even if it is not in the aqueous

1:56solution , we have defined it in this

1:58way to define a 3 - step reaction . Now ,

2:01let me briefly explain the content that

2:03follows , and also the content that will

2:05follow . In fact , understanding this

2:07Breistedt definition is a little

2:09important . The reason is that , in the

2:11last lesson , I think we discussed the

2:12importance of the three substances . And

2:15we talked about how substances and

2:16chemicals are in a theoretically

2:18unified relationship . This means that

2:20there is a possibility that acids and

2:22chemicals will be involved in this

2:24chemical reaction . And when oxides are

2:27involved , it becomes a little difficult

2:29to understand without this Breistedt

2:30method , so please understand that a

2:32little . And this is a slightly

2:36irrelevant point to note , but here , the

2:383 is intentionally written as ' A ' and '

2:40E ' in English , but from now on , I will

2:42write this 3 - E in abbreviated form .

2:46That's because from now on , well , it's

2:48a hassle to write 1 for communism , weak

2:50communism , strong period , weak period ,

2:53so sometimes , for example , if it's

2:55communism , it's written as SA from

2:57strong acid , or if it's weak acid , it's

2:59written as WA from weak acid , so please

3:02be careful about that . So please don't

3:05be scared if you suddenly start writing

3:07it that way . Yes . That's what I mean .

3:09Yes . Well , for now , well , it's a

3:10trivial matter , but for now , that was

3:12the definition of 3 and postponement .

3:15Now , let's look at some typical 3 and

3:17postponement . We've looked at hydrides ,

3:21ternaries , and hydrides so far , so

3:23let's look at this again based on that

3:25knowledge . Yes . So , let's start with 3.

3:29Yes . What comes to mind when you hear

3:31the word communism ? For example ,

3:34there's cyclic acid . Well , there's

3:37cyclic arithmetic , but let's use hx for

3:40now . So , what is this x ? It's a halogen

3:44, and among halogens , chlorine , um , br ,

3:47let's think of it as an astringent

3:49element . Of course , you can see that

3:52acids are strong , but as we learned

3:54when we studied hydrides , the further

3:57down you go in the periodic table , the

3:59larger the atomic radius , and the more

4:01likely it is to release H. In other

4:03words , it becomes 3 , which is stronger

4:05than HCL , so HBRHi , um , astringent

4:07hydrogen . Keep this in mind as well .

4:11And the next one . Um , the second one

4:13that comes to mind is , for example ,

4:15miscarriage . And the third one . This is

4:18also a weak compound that I want you to

4:20remember . For the time being , these are

4:22the compounds that I want you to keep

4:24in mind at the exam level . Make sure

4:26you remember this . And then , what are

4:28weak compounds ? Think of everything

4:31else as weak . Well , I'll write down

4:35some specific examples of weak

4:37compounds , but for example , in terms of

4:39hydrides , there are HF , refractor

4:41hydrogen , etc. Refractor hydrogen is

4:43the only weak compound among hydrogen

4:45halides , so you should remember this .

4:49And next , um , H2S hydrogen . Yes . This

4:52was also a weak calculation . I think we

4:54learned about this in hydrides . And

4:56next , just to be clear , let me give you

4:59one example from among the compounds ,

5:01um , H2CO3 monoacid , etc. Well , I've

5:03given a few examples this time , but if

5:05these aren't included , remember that

5:08it's basically a weak calculation . Yes .

5:10And next . Circular period . Let me write

5:13down what the co-flame was like . Ah ,

5:16it's a compound of an alkali metal . Yes

5:21. This is a little hard to see , but M ,

5:23this is derived from metal , but think

5:24of it as an alkali metal . Compounds

5:26such as lithium , sodium , and potassium .

5:30Of course , there are more than this ,

5:31but these are strong flames . And

5:36another co-flame that I want you to

5:38remember is a compound of an alkali

5:39metal . Yes . This is also calcium ,

5:44strontium , and barium . Is that okay ?

5:47And of course , the weak ones are the

5:49others . Yes . So , I'd like to give some

5:53specific examples here as well . Yes .

5:55For example , when it comes to hydride

5:58additives , of course , it's Group 15. Um

6:00, for example , ammonia . Well , there was

6:03also PH phosphine , but I won't go into

6:05that . Well , the only thing that comes

6:08up is ammonia , so don't worry about

6:09that . And then , when it comes to weak

6:11ones on the aquatic chemical side , well

6:13, we didn't deal with them in the

6:14aquatic chemical industry , but they're

6:16anything other than alkali metals or

6:18alkali metals . For example , aluminum

6:20hydroxide . Basically , you can think of

6:26most metallic aquatic chemicals as weak

6:28ones . Is that right ? Yes . So , basically

6:31, remember these as strong ones and

6:33remember that the others are weak ones .

6:36Yes . And here , I'd like to talk about

6:38one additional piece of knowledge , or

6:40rather , a small , important point to

6:42note . Um , this time I'd like to talk

6:45about miscarriage . By the way ,

6:48miscarriage , maybe you've all heard the

6:50rumor that a cerebral miscarriage is a

6:52weak birth . For those who haven't heard

6:55of it , let me briefly explain . As I

6:57said in the participation class ,

6:59miscarriage is a liquid at elevated

7:01temperatures . That's why it's possible

7:04to create a very concentrated

7:06miscarriage that's 98 % miscarriage .

7:08That's what we call miscarriage acid .

7:11So , what kind of state is miscarriage

7:13acid in water ? There's almost no water .

7:16Now , let me compare this to the

7:18definition I gave earlier . In order for

7:21this to become 3 , H + needs to be

7:23released in the water , but there's no

7:25water at all . H + is actually in the

7:29form of an oxonium ion called H3O + , so

7:32it's difficult to electrolyze this H +

7:34unless there's water to push it . So , in

7:38terms of pH , miscarriage acid is

7:40actually completely incapable of

7:42electrolyzing . In reality , you want to

7:44electrolyze 100 % with symbiosis , but

7:46there is no water , so electrolysis

7:48cannot be done at all and the pH does

7:50not rise easily . That's why I think

7:52there are sometimes teachers who teach

7:54that symbiosis is a weak production ,

7:56but personally , I think it's better to

7:57have a symbiotic mindset even if

7:59symbiosis is used . What I mean is , of

8:02course , this one doesn't reward H +

8:04very much , but it has an incredible

8:06ability to give H + . So , in terms of

8:10Brønstedt's 3 , this one is a strong 3.

8:12It just happens that the recipient

8:14isn't in the water yet , so this one

8:16doesn't show any approval . So , for

8:21example , if you put E in symbiosis with

8:23symbiosis , it will react explosively ,

8:25and in the end , its ability as a 3 is

8:27quite high , so , well , in order not to

8:29lose the image of the reaction , I think

8:32it's important to remember that even

8:34symbiosis is strong . So to be precise ,

8:37I think it would be best to think that

8:39PH cannot be used to measure pH . Well ,

8:41ammonia is the same . Ammonia in the

8:44form of ammonia does not emit OH - in the

8:46first place , so it is counted as an OH -

8:48, and ammonia in the form of ammonia ,

8:50which cannot be measured by PH , is

8:51normally counted as an OH - , so you can

8:53think of it as something close to that .

8:55Yes . Well , I know I may go into too

8:57much detail for a science-oriented

8:58audience , but these were just a few

8:59minor points to keep in mind . Anyway ,

9:01getting back to the topic , please make

9:03sure you fully understand the

9:04definition of a 3 - cycle and the typical

9:063 - cycles . Yes . Now that we've reviewed

9:11to some extent , I'd like to do a more

9:13detailed explanation of how to write

9:14reactions , a science-oriented version .

9:18Well then , let's write on the

9:19blackboard . Now , let's review how to

9:22write reaction equations , including

9:24some new content as well . Yes . First ,

9:27I've written down the key points here .

9:29It's the balance between the H + and OH

9:31- . This is exactly the same as what we

9:33learned in basic science . It's about

9:35counting the number of H + and OH - and

9:37making them equal . And this time ,

9:40there's a little extra content . I wrote

9:43that when a triangular object appears ,

9:45we should formally consider adding

9:46water . Let's look at a concrete example

9:49to see what this means . This time , I'll

9:51look at three concrete examples , so

9:52please watch until the end . The third

9:54one is the most important . So let's

9:56look at the first one first . Yes . We

9:58added CO2 to a certain amount of NaOH

10:00aqueous solution . Yes . The problem this

10:03time is that CO2 appeared here . Yes .

10:08And CO2 is , of course , CO2 , and as we

10:10learned in the triangular object class ,

10:12if we added water to this , it would be

10:15a simple acid . Since that simple acid

10:18and CO2 are in a formal relationship ,

10:20this becomes 2/3 . I think we learned

10:23that . And let's go back to the point

10:25again . When an acid appears , what does

10:27it mean to add water to it ? In this

10:32case , CO2 is reacting here , but let's

10:34think of it as if it had reacted once

10:36after it had been added to the water

10:38solution . Well , this reaction is

10:42actually a single reaction , so it's

10:44perfectly natural to think of it as

10:46reacting after it had been added to the

10:48water solution . So let's write it down

10:50here . First , we've already learned how

10:54to write this when CO2 enters the water

10:56and combines with it . Then , let's think

11:01about the H2CO3 and NaOH that were

11:03created in this way . From here on ,

11:05we'll naturally follow the rules . Let's

11:07think about the balance between the H +

11:09that this one produces and the OH - that

11:10this one produces . I'll just write this

11:13right away , but H2CO3 produces two

11:15parts . In order for the 1+ and the

11:18middle part to occur exactly , we need

11:20two parts of NaOH . So these react , and

11:23then the middle part reacts like this .

11:27Yes . Is that okay ? When two H + and two

11:30H - join together to form two water

11:32molecules , the rest dissolves like this

11:34. Yes . Once you have two reaction

11:37equations like this , this is the last

11:39step . Let's add these together . When

11:42you create equations for oxidative

11:43reactions , I think there was a similar

11:45addition method , and you add them

11:46together like this . Of course , you can

11:48eliminate the overlapping ones . You can

11:52eliminate the overlapping ones on

11:53opposite sides like this . Then , add the

11:56remaining ones below to complete the

11:58reaction equation . Yes . That's it . Well

12:01, the content may be a little new , but

12:03what you're doing is a combination of

12:04what you practiced when you learned

12:06about three additives and what you

12:07learned about intermediate reactions ,

12:09so I don't think there's any problem at

12:10all . And I'd like to practice two more

12:12things , so let's delete this one for

12:14now and look at two more specific

12:16examples . Now , let's look at the second

12:18specific example . Yes . It's a circle

12:20calculation of the amount of

12:21sufficiency . Let's see what happens

12:23when we add CAO , calcium oxide , to this

12:26. First , of course , we're curious about

12:28this CAO trigonometric compound . Let's

12:30process this . Since we just did it ,

12:32let's do it quickly . Yes . It's CO . This

12:36is a trigonometric compound , so let's

12:38first consider it formally by adding

12:40water . Yes , when water is added to this

12:42, it becomes like this . Yes , if we

12:45write it like this , it becomes a

12:47hydroxy compound , so let's neutralize

12:49this hydroxy compound and the cyclone .

12:53I'll write it first , but for COH2 , if

12:55there are two parts of this , it can be

12:57neutralized with two parts of OH - , so

12:59it becomes 2HCl . Now , let's write the

13:03rest . Yes . I've written it like this .

13:06All that's left is to add the variable

13:08sides . I'll do it again carefully , but

13:11yes , let's delete the overlapping ones .

13:14And here , water is also overlapping , so

13:16if we delete it , the rest will be

13:18written as usual by adding them . Yes .

13:22It looks like this . It doesn't really

13:24matter whether the acid is positive or

13:26the ternary compound is the current

13:28line . Just write it like this . Is that

13:30okay ? Then let's look at the last third

13:32example . Yes . Well then , let's look at

13:36the third one . This also writes the

13:38reaction equation . Yes . Well , I'll

13:40write it . Please follow along as if it

13:42were a review . First , SiO2 . If you

13:46formally add water to SiO2 . Yes . Then ,

13:49what will happen is , of course , H2Sio3 .

13:53Yes . I think this was written in the

13:55aquatic compound section when the

13:56ternary compound was added . Is that

13:58okay ? Then , since this is in the 2 : 3

14:00state , all we have to do is consider

14:02the neutralization reaction with it . If

14:05there are two for one H2SIO3 , the

14:07neutralization is complete , right ? And

14:11what comes out is two waters and the

14:13rest , so we add them like this . Yes .

14:16It's exactly as the back is Ollie said .

14:18All that's left is to add them together

14:20by changing the sides . Of course , if

14:22you erase the overlapping part , you'll

14:24also erase the water , which will result

14:26in this . Yes . Is that okay ? I think

14:31I've followed the steps . However ,

14:33there's just one thing to note here .

14:36It's a bit of a technical point , but

14:37I'll mention it anyway . Let's review

14:40this from 01 again . Yes . CO2 has been

14:44dropped into NaOH . It looks like it's

14:48reacting when it combines with water .

14:51On the other hand , this one also adds

14:53CAO powder or a solid to HCl . When it

14:57combines with water , it becomes this ,

14:59and it looks like it reacted . How about

15:02this ? For example , it's written as if

15:05SIO2 has entered water , formed this

15:07shape , and reacted . Just remember this .

15:13SIO2 is a crystal , right ? To be more

15:16specific , for example , water droplets

15:19and things like that are SIO2 . Is that

15:21okay ? Or it could be contained in glass

15:23. In this way , no matter how you look

15:26at it , this thing can't actually bond

15:28directly with water . So , in reality ,

15:31this two-step reaction isn't actually

15:33happening . That's why I've been saying

15:37" formally " all along . As you can see ,

15:40the reaction that's happening is a

15:41neutralization reaction between a

15:43positive ternary additive called SiO2

15:45and a positive ternary additive called

15:47cyclohexane , so there's no problem at

15:49all . In the process of writing the

15:51reaction equation , it's much easier to

15:52write the reaction equation if you

15:54formally add water and think of a

15:55reaction that doesn't actually happen

15:57as having happened . So , even if it's an

15:59unlikely reaction , let's just write it

16:01down like this for now . Is that okay ?

16:04Yes . As you can see , this is a bit of a

16:06nerdy point to note , but things like

16:08this do happen , so please be careful ,

16:10even though this is strictly for

16:12science students . On the other hand ,

16:13there are no more difficult questions

16:15than this when it comes to the reaction

16:16equation for the intermediate reaction ,

16:18so I think it would be good if you

16:19could write it down properly up to this

16:20point . Well , I apologize for repeating

16:23myself , but if you don't understand the

16:24phenomenon , if you don't understand

16:26that you're doing something that isn't

16:28happening , you might be surprised when

16:30the time comes , so I'd appreciate it if

16:31you could just keep that in mind and

16:33leave it as a point of caution . Okay ,

16:36so that's it for this time . I think the

16:39video ended up being quite short , but

16:41that was how to write a neutralization

16:43reaction equation . I'd be happy if you

16:45could just keep it in the form of rules

16:47and exceptions . Okay . So , this is how

16:50to write the first half of the turn

16:52postponement reaction , the middle

16:53reaction . Please listen carefully so

16:55you can do this . As a preview for the

16:57next episode , next time we'll be

16:59looking at the weak-weak phase , the

17:00favorable reaction . Actually , that's

17:02what I want to focus on the most this

17:04time . In fact , 3 and Iki can cause a

17:06weak-phase favorable reaction in

17:07addition to the neutralization reaction

17:09. And in that direction science , it's

17:11no exaggeration to say that this

17:12weak-phase favorable reaction on the

17:14latter half of the line is actually

17:15more important , so let's work hard

17:17together next time so that we can do

17:18this properly . So , if you enjoyed this

17:20lesson even a little , please subscribe

17:21to the channel , leave a comment , and

17:23give it a thumbs up . Well , that's all

17:24for today . Thank you for your hard work

17:26.

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